Thermodynamics And Statistical Mechanics Codexery

Osmosis

Spontaneous solvent movement across a semipermeable membrane.

Osmosis

Osmosis is the spontaneous net movement of solvent molecules through a selectively permeable membrane from a region of high water potential (lower solute concentration) to a region of low water potential (higher solute concentration), in the direction that tends to equalize solute concentrations. It is a vital process in biological systems, providing the primary means by which water is transported into and out of cells, and can be made to do work.

field
Physical chemistry, biology
known_for
Spontaneous solvent movement across semipermeable membranes
key_property
Colligative property (depends on molar concentration, not solute identity)

Lore & Background

Some kinds of osmotic flow have been observed since ancient times, e.g., on the construction of Egyptian pyramids. The word 'osmosis' descends from 'endosmose' and 'exosmose', coined by French physician René Joachim Henri Dutrochet from Greek words meaning 'within', 'outer', and 'push'.

Reader's Guide

Osmosis is a fundamental process in both physical chemistry and biology. It describes the movement of a solvent—typically water in biological systems—across a selectively permeable membrane toward a higher concentration of solute. This process is driven by a pressure gradient rather than random molecular diffusion, and it can be opposed by applying external pressure, defined as osmotic pressure. Osmotic pressure is a colligative property, meaning it depends only on the molar concentration of the solute, not its identity. In living organisms, osmosis is essential for maintaining cell hydration, turgor pressure in plants, and the balance of water and solutes across cell membranes. Imbalances can lead to cellular dysfunction or death, as seen when freshwater or saltwater fish are placed in water of maladaptive salinity. The mechanism of osmosis has been debated, with earlier models (diffusion and 'bound water') refuted; current understanding emphasizes thermodynamic and mechanical explanations involving chemical potential and pressure differences.

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